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Structural and electrical characterization of cadmium phosphate glasses doped with different concentration of sodium chloride

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26620%2F24%3APU155963" target="_blank" >RIV/00216305:26620/24:PU155963 - isvavai.cz</a>

  • Alternative codes found

    RIV/68081731:_____/24:00602200

  • Result on the web

    <a href="https://iopscience.iop.org/article/10.1088/1402-4896/ad8822" target="_blank" >https://iopscience.iop.org/article/10.1088/1402-4896/ad8822</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1088/1402-4896/ad8822" target="_blank" >10.1088/1402-4896/ad8822</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Structural and electrical characterization of cadmium phosphate glasses doped with different concentration of sodium chloride

  • Original language description

    The electrical characteristics of cadmium phosphate glasses doped with varying concentrations of sodium chloride [ Cd-3( PO4)(2)](1-x) [ NaCl](x) , where x = 0, 2, 4 ,6 mol.% NaCl, were investigated with respect to both dopant levels and temperature. Electrical impedance spectroscopy was employed, and impedance measurements were taken across the frequency spectrum from 10(2) Hz to 10(6) Hz. Samples were characterized by scanning electron microscopy-energy dispersive x-ray spectroscopy, x-ray diffraction analysis and Fourier Transform Infrared Spectroscopy. The fi ndings revealed a decrease in bulk resistance with increasing temperature and dopant concentration, indicating a rise in DC- conductivity and suggesting a semiconducting behavior in the material. Moreover, the activation energy values were noted to decrease as dopant concentration increased. Analysis of the AC-conductivity variation with frequency delineated two distinct regions: a low-frequency region where AC-conductivity increased with frequency, indicative of a "pumping force" effect aiding charge carrier movement through various conduction states, and a high-frequency region or frequency-independent zone signifying a transition towards a more ohmic behavior in the material. The study highlighted a decrease in both the dielectric constant and dielectric loss with rising temperature and frequency across all dopant concentrations. Furthermore, the Reaction Coefficient "s" was found to be less than one, suggesting that the conduction mechanism can be elucidated in terms of the Correlated Barrier Hopping ( CBH ) model.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10300 - Physical sciences

Result continuities

  • Project

    <a href="/en/project/LM2023051" target="_blank" >LM2023051: Research infrastructure CzechNanoLab</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2024

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    PHYSICA SCRIPTA

  • ISSN

    0031-8949

  • e-ISSN

    1402-4896

  • Volume of the periodical

    99

  • Issue of the periodical within the volume

    12

  • Country of publishing house

    SE - SWEDEN

  • Number of pages

    14

  • Pages from-to

    „“-„“

  • UT code for WoS article

    001351324500001

  • EID of the result in the Scopus database

    2-s2.0-85209565222