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Development of a fast UHPLC-MS/MS for the analysis of selected priority micropollutants in wastewater samples

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60460709%3A41330%2F21%3AN0000123" target="_blank" >RIV/60460709:41330/21:N0000123 - isvavai.cz</a>

  • Alternative codes found

    RIV/60460709:41330/19:79758

  • Result on the web

    <a href="https://www.tandfonline.com/doi/full/10.1080/03067319.2019.1660874" target="_blank" >https://www.tandfonline.com/doi/full/10.1080/03067319.2019.1660874</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1080/03067319.2019.1660874" target="_blank" >10.1080/03067319.2019.1660874</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Development of a fast UHPLC-MS/MS for the analysis of selected priority micropollutants in wastewater samples

  • Original language description

    In recent years, there have been many reports on the presence of organic compounds in different compartments of the aquatic environment. The subject of our research was the development of a new method for the determination of selected organic micropollutants and their transformation products in wastewater samples. A rapid and sensitive ultra-high performance liquid chromatographic method coupled with tandem mass spectrometry has been developed and used for the separation and determination of 1H-benzotriazole, imidacloprid and clarithromycin in wastewater samples. The analytes were separated on a ZORBAX SB-C3 column with a gradient elution within 3,0 min. The analytes were isolated from wastewater samples by solid-phase extraction. Extraction was carried out on the Oasis HLB cartridges and methanol:acetone (1:1, v/v) was used for elution. The working ranges of the developed method were 1-100 ng L-1. The recovery ranged from 62% to 102% and intra- and inter-day precision was lower than 13% for all analytes. Finally, the optimised method was applied for the determination of the organic micropollutants in wastewater samples: (artificial) raw wastewater, wastewater treated using aerated activated sludge method and wastewater from an Upper Silesia wastewater treatment plant. In addition, transformation products of the analytes in the treated wastewater samples were tentatively identified.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10406 - Analytical chemistry

Result continuities

  • Project

  • Continuities

    S - Specificky vyzkum na vysokych skolach

Others

  • Publication year

    2021

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY

  • ISSN

    0306-7319

  • e-ISSN

    1029-0397

  • Volume of the periodical

    101

  • Issue of the periodical within the volume

    1

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    20

  • Pages from-to

    59-78

  • UT code for WoS article

    000485959600001

  • EID of the result in the Scopus database

    2-s2.0-85072046649