2-(Perfluoroalkyl)ethyl Triflates, Building Blocks for the Synthesis of Bis(polyfluoroalkylated) Cyclopentadienes.

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F01%3A00004331" target="_blank" >RIV/60461373:22310/01:00004331 - isvavai.cz</a>

Alternative codes found

RIV/67985858:_____/01:27013116

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

2-(Perfluoroalkyl)ethyl Triflates, Building Blocks for the Synthesis of Bis(polyfluoroalkylated) Cyclopentadienes.

Original language description

Fluorinated building blocks, 2-(perfluorohexyl)ethyl triflate (11a) and 2-(perfluorooctyl)ethyl triflate (11b) were prepared from the corresponding fluoroalkanols and triflic anhydride. Fluorinated triflates 11 were employed for the preparation of bis(polyfluoroalkylated) cyclopentadienes 9, which are potential ligands for homogeneous catalysts used in fluorous biphase systems. Fluorotriflates 11 are also excellent substrates for the preparation of various polyfluorinated compounds, e.g. nitriles or azides, by nucleophilic substitution.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CC - Organic chemistry

OECD FORD branch

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Project

<a href="/en/project/GA203%2F99%2F0135" target="_blank" >GA203/99/0135: Transition metal complexes with cyclopentadienyl ligands for catalysis in fluorous biphase systems</a><br>

Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2001

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Synlett

ISSN

0936-5214

e-ISSN

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Volume of the periodical

N

Issue of the periodical within the volume

5

Country of publishing house

DE - GERMANY

Number of pages

3

Pages from-to

685-687

UT code for WoS article

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EID of the result in the Scopus database

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