Homogeneous Lewis and Brønsted acids as catalysts for β-pinene oxide rearrangement to prepare myrtenol and myrtanal
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F20%3A43920839" target="_blank" >RIV/60461373:22310/20:43920839 - isvavai.cz</a>
Result on the web
<a href="https://www.sciencedirect.com/science/article/abs/pii/S2468823120302017" target="_blank" >https://www.sciencedirect.com/science/article/abs/pii/S2468823120302017</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.mcat.2020.110945" target="_blank" >10.1016/j.mcat.2020.110945</a>
Alternative languages
Result language
angličtina
Original language name
Homogeneous Lewis and Brønsted acids as catalysts for β-pinene oxide rearrangement to prepare myrtenol and myrtanal
Original language description
Myrtenol and myrtanal find their utilization as fine chemicals or intermediates for the synthesis of food additive myrtanol. β-Pinene oxide rearrangement was studied using homogeneous Lewis and Brønsted acids as catalysts for the production of these compounds. The composition of reaction products depended on the type of active sites. Lewis active sites favoured the formation of myrtanal while in presence of Brønsted active sites undesirable perillyl aldehyde and perillyl alcohol were formed to a high extent. Optimal reaction conditions for myrtenol and myrtanal preparation were found. With 5 mol.% of anhydrous SnCl2 as Lewis acid catalysts and 1,4-dioxane as the solvent β-pinene oxide achieved total conversion with 95% selectivity to desired products. © 2020 Elsevier B.V.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10401 - Organic chemistry
Result continuities
Project
<a href="/en/project/LO1613" target="_blank" >LO1613: Future materials</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Molecular Catalysis
ISSN
2468-8231
e-ISSN
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Volume of the periodical
492
Issue of the periodical within the volume
August
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
6
Pages from-to
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UT code for WoS article
000549100200005
EID of the result in the Scopus database
2-s2.0-85084676431