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Homogeneous Lewis and Brønsted acids as catalysts for β-pinene oxide rearrangement to prepare myrtenol and myrtanal

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F20%3A43920839" target="_blank" >RIV/60461373:22310/20:43920839 - isvavai.cz</a>

  • Result on the web

    <a href="https://www.sciencedirect.com/science/article/abs/pii/S2468823120302017" target="_blank" >https://www.sciencedirect.com/science/article/abs/pii/S2468823120302017</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.mcat.2020.110945" target="_blank" >10.1016/j.mcat.2020.110945</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Homogeneous Lewis and Brønsted acids as catalysts for β-pinene oxide rearrangement to prepare myrtenol and myrtanal

  • Original language description

    Myrtenol and myrtanal find their utilization as fine chemicals or intermediates for the synthesis of food additive myrtanol. β-Pinene oxide rearrangement was studied using homogeneous Lewis and Brønsted acids as catalysts for the production of these compounds. The composition of reaction products depended on the type of active sites. Lewis active sites favoured the formation of myrtanal while in presence of Brønsted active sites undesirable perillyl aldehyde and perillyl alcohol were formed to a high extent. Optimal reaction conditions for myrtenol and myrtanal preparation were found. With 5 mol.% of anhydrous SnCl2 as Lewis acid catalysts and 1,4-dioxane as the solvent β-pinene oxide achieved total conversion with 95% selectivity to desired products. © 2020 Elsevier B.V.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10401 - Organic chemistry

Result continuities

  • Project

    <a href="/en/project/LO1613" target="_blank" >LO1613: Future materials</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2020

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Molecular Catalysis

  • ISSN

    2468-8231

  • e-ISSN

  • Volume of the periodical

    492

  • Issue of the periodical within the volume

    August

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    6

  • Pages from-to

  • UT code for WoS article

    000549100200005

  • EID of the result in the Scopus database

    2-s2.0-85084676431