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RESPONSE DYNAMICS OF THE HYDROGEN PEROXIDE; THIOSULPHATE; SULFITE REACTION

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F10%3A00023250" target="_blank" >RIV/60461373:22340/10:00023250 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    RESPONSE DYNAMICS OF THE HYDROGEN PEROXIDE; THIOSULPHATE; SULFITE REACTION

  • Original language description

    This work is focused on experiments with a complex reaction of hydrogen peroxide with thiosulphate and sulfite in acidic solution carried out in a continuous flow stirred tank reactor. This reaction belongs to the family of pH oscillators because the concentration of hydrogen ion exhibits periodic changes in time. The observed dynamical regimes of this reaction are multiple steady states and periodic oscillations under isothermal conditions. The aim of this work is the study of response dynamics of thereaction to single-pulsed forcing by additions of hydrogen peroxide and sodium hydroxide. Hydrogen peroxide constitutes one of the basic reactants and hydroxide ions provide one of the possible ways for consumption of hydrogen ions during the reaction (negative feedback). The concentration increment due to the pulse constitutes the control parameter. The method is exploring phase advance or phase delay of periodically oscillating system caused by external perturbations. Responses to puls

  • Czech name

  • Czech description

Classification

  • Type

    D - Article in proceedings

  • CEP classification

    CI - Industrial chemistry and chemical engineering

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)<br>S - Specificky vyzkum na vysokych skolach

Others

  • Publication year

    2010

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Article name in the collection

    Proceedings of the 37th International Conference of Slovak Society of Chemical Engineering, 2010

  • ISBN

    978-80-227-3290-1

  • ISSN

  • e-ISSN

  • Number of pages

    10

  • Pages from-to

  • Publisher name

    Slovak Society of Chemical Engineering

  • Place of publication

    Bratislava

  • Event location

    Tatranské Matliáre

  • Event date

    Jan 1, 2010

  • Type of event by nationality

    WRD - Celosvětová akce

  • UT code for WoS article