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Phase response dynamics of a pH-oscillatory reaction in a flow stirred reactor

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F11%3A43892251" target="_blank" >RIV/60461373:22340/11:43892251 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Phase response dynamics of a pH-oscillatory reaction in a flow stirred reactor

  • Original language description

    The reaction of hydrogen peroxide with thiosulphate and sulfite in acidic solution is a pH-oscillatory reaction characterized by marked pH variations in time implying autocatalytic nature of hydrogen ions. When carried out in a continuous-flow stirred tank reactor this reaction provides nonlinear dynamical regimes such as periodic, oscillations, chaotic behaviour and various stable steady states, which may coexist over a range of operating conditions. The aim of this work is the study of response dynamics of the reaction to single pulse forcing by additions of chosen reaction specie. The concentration increment due to the pulse constitutes the variable parameter. The experimental method is based on external perturbations of periodically oscillating system causing phase advance or phase delay of the system. Results of this work are the phase transition curves obtained from stimulation of the pH-oscillations in the hydrogenperoxide-thiosulphate-sulfite system reaction with brief single p

  • Czech name

  • Czech description

Classification

  • Type

    D - Article in proceedings

  • CEP classification

    CI - Industrial chemistry and chemical engineering

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)<br>S - Specificky vyzkum na vysokych skolach

Others

  • Publication year

    2011

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Article name in the collection

    Proceedings 2011 World Congress on Engineering and Technology

  • ISBN

    978-1-61284-362-9

  • ISSN

  • e-ISSN

  • Number of pages

    4

  • Pages from-to

    656-659

  • Publisher name

    Institute of Electrical and Electronics Engineers, Inc.

  • Place of publication

    Bejing

  • Event location

    Shanghai

  • Event date

    Oct 28, 2011

  • Type of event by nationality

    WRD - Celosvětová akce

  • UT code for WoS article