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Effects of biofuel blends on performance of exhaust gas catalyst: Ethanol and acetaldehyde reactions

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F10%3A00023491" target="_blank" >RIV/60461373:22340/10:00023491 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Effects of biofuel blends on performance of exhaust gas catalyst: Ethanol and acetaldehyde reactions

  • Original language description

    The use of biofuels in internal combustion engines changes the composition of the engine exhaust gas. When burning a biofuel blend, significant amounts of oxygenated hydrocarbons such as alcohols, ethers and aldehydes are present in the exhaust gas. It is known, that these compounds influence catalytic processes in exhaust gas converters. In this work we propose a global kinetic model for ethanol and acetaldehyde oxidation on commonly used Pt, PtPd and Pd-based catalytic oxidation converters of automobile exhaust gases. The mechanism is based on two steps: (i) partial oxidation of ethanol to acetaldehyde, and (ii) complete oxidation of acetaldehyde to CO2 and H2O. Kinetic parameters of ethanol and acetaldehyde reactions are evaluated on the basis of laboratory light-off experiments with several catalytic monolith samples (noble metal loading 9-140 g/cft; Pt, Pd, and PtPd; at space velocity 30 000 - 240 000 h-1). Net formation of acetaldehyde from ethanol is observed around the light-of

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CI - Industrial chemistry and chemical engineering

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2010

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    SAE International Journal of Fuels and Lubricants

  • ISSN

    1946-3952

  • e-ISSN

  • Volume of the periodical

    3

  • Issue of the periodical within the volume

    1

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    13

  • Pages from-to

  • UT code for WoS article

  • EID of the result in the Scopus database