[6]Helicene as a novel molecular tweezer for the univalent silver cation: Experimental and theoretical study

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F15%3A43899445" target="_blank" >RIV/60461373:22340/15:43899445 - isvavai.cz</a>
Alternative codes found
RIV/60460709:41330/15:68295 RIV/60461373:22810/15:43899445
Result on the web
<a href="http://dx.doi.org/10.1016/j.molstruc.2015.04.022" target="_blank" >http://dx.doi.org/10.1016/j.molstruc.2015.04.022</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.molstruc.2015.04.022" target="_blank" >10.1016/j.molstruc.2015.04.022</a>

Result language
angličtina
Original language name
[6]Helicene as a novel molecular tweezer for the univalent silver cation: Experimental and theoretical study
Original language description
By employing electrospray ionization mass spectrometry (ES1-MS), it was proven experimentally that the [6]helicene-Ag+ complex (i.e.. (Ag(C26H16)](+)) exists in the gas phase. Further, applying quantum mechanical OFT calculations, the most probable structure of this cationic complex [Ag(C26H16)](+) was derived. Finally, in the solid state, the complex [6]helicene-silver perchlorate-monohydrate (i.e., C26H16-AgClO4-H2O), crystallizing in the monoclinic system with the centro-symmetric P2(1/)c space group, was prepared and analyzed by X-ray crystallography.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CB - Analytical chemistry, separation
OECD FORD branch
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Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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