Cation-pi interaction of the univalent silver cation with racemic [6]helicene in the gas phase and in the solid state
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22810%2F16%3A43901706" target="_blank" >RIV/60461373:22810/16:43901706 - isvavai.cz</a>
Alternative codes found
RIV/61388963:_____/16:00466148 RIV/60460709:41330/16:71239 RIV/60461373:22340/16:43901706
Result on the web
<a href="http://dx.doi.org/10.1016/j.poly.2016.05.016" target="_blank" >http://dx.doi.org/10.1016/j.poly.2016.05.016</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.poly.2016.05.016" target="_blank" >10.1016/j.poly.2016.05.016</a>
Alternative languages
Result language
angličtina
Original language name
Cation-pi interaction of the univalent silver cation with racemic [6]helicene in the gas phase and in the solid state
Original language description
Employing electrospray ionization mass spectrometry (ESI-MS), it was proven experimentally that the [6]helicene - Ag+ complex (i.e., [Ag(C26H16)](+)) exists in the gas phase. Further, applying quantum mechanical DFT calculations, the most probable structure of this cationic complex [Ag(C26H16)](+) was derived. Finally, in the solid state, the complex [6]helicene - silver hexafluoroantimonate - monohydrate (i.e., C26H16 - AgSbF6 - H2O), crystallizing in the monoclinic system with the centrosymmetric space group P2(1)/c, was prepared and analyzed by X-ray crystallography.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CB - Analytical chemistry, separation
OECD FORD branch
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Result continuities
Project
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Continuities
S - Specificky vyzkum na vysokych skolach
Others
Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Polyhedron
ISSN
0277-5387
e-ISSN
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Volume of the periodical
117
Issue of the periodical within the volume
neuvedeno
Country of publishing house
GB - UNITED KINGDOM
Number of pages
6
Pages from-to
1-6
UT code for WoS article
000384384500001
EID of the result in the Scopus database
2-s2.0-84973353680