Experimental and theoretical study on cation-pi interaction of Ag with [6]helicene
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F16%3A43901626" target="_blank" >RIV/60461373:22340/16:43901626 - isvavai.cz</a>
Alternative codes found
RIV/60460709:41330/16:71237 RIV/00216208:11310/16:10323244
Result on the web
<a href="http://link.springer.com/article/10.1007/s11224-015-0595-7?wt_mc=internal.event.1.SEM.ArticleAuthorAssignedToIssue" target="_blank" >http://link.springer.com/article/10.1007/s11224-015-0595-7?wt_mc=internal.event.1.SEM.ArticleAuthorAssignedToIssue</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s11224-015-0595-7" target="_blank" >10.1007/s11224-015-0595-7</a>
Alternative languages
Result language
angličtina
Original language name
Experimental and theoretical study on cation-pi interaction of Ag with [6]helicene
Original language description
By employing electrospray ionization mass spectrometry, it was proven experimentally that the [6]helicene-Ag+ complex (i.e., [Ag(C26H16)](+)) exists in the gas phase. Further, applying quantum mechanical DFT calculations, the most probable structure of this cationic complex [Ag(C26H16)](+) was derived. Finally, in the solid state, the complex [6]helicene-silver triflate-monohydrate (i.e., C26H16-AgCF3SO3-H2O), crystallizing in the monoclinic system with the centro-symmetric P2(1)/c space group, was prepared and analyzed. The characteristic feature of this complex packing in the solid state is the formation of the separated [6]helicene and silver triflate domains. In both of these binding modes, the investigated [6]helicene ligand functions as a molecular tweezer for the univalent silver cation.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CB - Analytical chemistry, separation
OECD FORD branch
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Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Structural Chemistry
ISSN
1040-0400
e-ISSN
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Volume of the periodical
27
Issue of the periodical within the volume
2
Country of publishing house
US - UNITED STATES
Number of pages
9
Pages from-to
627-635
UT code for WoS article
000372291500019
EID of the result in the Scopus database
2-s2.0-84961171497