Contribution to cation-pi interaction of the univalent silver cation with racemic [7]helicene in the solid state
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F17%3A43903848" target="_blank" >RIV/60461373:22340/17:43903848 - isvavai.cz</a>
Alternative codes found
RIV/60460709:41330/17:74570 RIV/67985858:_____/17:00507129
Result on the web
<a href="https://link.springer.com/article/10.1007%2Fs11224-015-0679-4" target="_blank" >https://link.springer.com/article/10.1007%2Fs11224-015-0679-4</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s11224-015-0679-4" target="_blank" >10.1007/s11224-015-0679-4</a>
Alternative languages
Result language
angličtina
Original language name
Contribution to cation-pi interaction of the univalent silver cation with racemic [7]helicene in the solid state
Original language description
Yellow crystals of the complex [7]helicene-silver perchlorate (i.e., C30H18-AgClO4 or more accurately [Ag(eta(4)-C30H18)]ClO4, respectively), crystallizing in the monoclinic system with the centrosymmetric P2(1)/c space group, where a = 14.4230(3) , b = 10.2804(3) , c = 15.2541(4) , and beta = 91.856(2)A degrees, were prepared by slow evaporation of the solvent from a solution obtained by mixing equimolecular amounts of racemic [7]helicene and silver perchlorate in toluene at ambient temperature. Characteristic feature of the complex packing in the solid state is the formation of infinite antiparallel layers of dimeric structures of the proven complex. The investigated [7]helicene ligand in the racemic form functions as a molecular tweezer for the univalent silver cation.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10406 - Analytical chemistry
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Structural Chemistry
ISSN
1040-0400
e-ISSN
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Volume of the periodical
28
Issue of the periodical within the volume
3
Country of publishing house
US - UNITED STATES
Number of pages
5
Pages from-to
873-877
UT code for WoS article
000400574100031
EID of the result in the Scopus database
2-s2.0-85018728533