Observation and Theoretical Description of Periodic Geometric Rearrangement in Electronically Excited Nonstoichiometric Sodium-Fluoride Clusters.

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F02%3A54020247" target="_blank" >RIV/61388955:_____/02:54020247 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Observation and Theoretical Description of Periodic Geometric Rearrangement in Electronically Excited Nonstoichiometric Sodium-Fluoride Clusters.

Original language description

We present two-color fs pump-probe spectra of Na2F which were recorded by employing excitation wavelengths around 1208 nm (pump) and ionization wavelengths around 405 nm (probe). The observed oscillatory structure of the signal with a period of 185 fs shows an excellent agreement with our simulated spectra. The employed ab initio Wigner distribution approach provides clear evidence that this observation is caused by photoinduced metal bond breaking followed by a butterfly-type periodic geometric rearrangement.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CF - Physical chemistry and theoretical chemistry

OECD FORD branch

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Project

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Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2002

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Physical Review Letters

ISSN

0031-9007

e-ISSN

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Volume of the periodical

89

Issue of the periodical within the volume

21

Country of publishing house

US - UNITED STATES

Number of pages

4

Pages from-to

"213404.1"-"213404.4"

UT code for WoS article

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EID of the result in the Scopus database

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