Dynamics of Chemical and Charge Transfer Reactions of Molecular Dications: Part V. An Experimental and Theoretical Study of Reactions between CHCl2+ and Ar, Kr and Xe.

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F03%3A54030096" target="_blank" >RIV/61388955:_____/03:54030096 - isvavai.cz</a>

Result on the web

—

DOI - Digital Object Identifier

—

Result language

angličtina

Original language name

Dynamics of Chemical and Charge Transfer Reactions of Molecular Dications: Part V. An Experimental and Theoretical Study of Reactions between CHCl2+ and Ar, Kr and Xe.

Original language description

Non-dissociative charge transfer processes between the dication CHCl2+ and noble gases Ar, Kr, and Xe were investigated in crossed-beam scattering experiments. Translational energy distributions of the product CHCl+ revealed that two isomers of CHCl2+ ofdifferent energetics were taking part in these processes. In reactions with Ar, the charge transfer products are formed mainly in reactions of the CCl-H2+ isomer in the ground (iS0) and first excited (iT1) state, leading to the ground (iD0) and first excited (iD1) state of the cation CCl-H+. Part of the vibrationally excited product (iD0) may dissociate further to give CCl+ + H. The main reaction in the system with Ar is, however, an impulsive proton transfer process of the other isomer, H-CCl2+(S0) leading to CCl+ + ArH+. The prevailing reaction with Kr is charge transfer leading to dication-cations transition CClH2+(CClH+(iD0), CClH2+(iS0)&61614; CClH+(iD1), and CClH2+(iT0)61614;CClH+(iD1) and Kr+ in both spin-orbit states.

Czech name

—

Czech description

—

Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CF - Physical chemistry and theoretical chemistry

OECD FORD branch

—

Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2003

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Physical Chemistry Chemical Physics

ISSN

1463-9076

e-ISSN

—

Volume of the periodical

5

Issue of the periodical within the volume

N/A

Country of publishing house

GB - UNITED KINGDOM

Number of pages

8

Pages from-to

2988-2995

UT code for WoS article

—

EID of the result in the Scopus database

—