Dynamics of Chemical and Charge Transfer Reactions of Molecular Dications: IV. Proton Transfer and Reactions of Dication Isomers in the CHCl2+ +D2 System.
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F03%3A54030164" target="_blank" >RIV/61388955:_____/03:54030164 - isvavai.cz</a>
Result on the web
—
DOI - Digital Object Identifier
—
Alternative languages
Result language
angličtina
Original language name
Dynamics of Chemical and Charge Transfer Reactions of Molecular Dications: IV. Proton Transfer and Reactions of Dication Isomers in the CHCl2+ +D2 System.
Original language description
Chemical reactions and charge transfer processes in the system CHCl2+ + D2 were investigated in crossed beam scattering experiments. Experimental data were complemented by theoretical calculations of the energetics of the species involved and by calculations of stationary points on the dication potential energy surfaces. The main reaction products were the cations CHCl+, CHDCl+, and CCl+. Integral cross sections for formation of these species were determined over the collision energy range 0.4-2.5 eV (center-of-mass, C.M.). Two isomers of the reactant dication were identified, with the H-atom bonded either to C (HCCl2+) or to Cl (CClH2+). The isomer CClH2+, of a higher ionization energy than HCCl2+, was found to be responsible for most of the charge transfer product (formation of the ground and excited states of CClH+).
Czech name
—
Czech description
—
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
—
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2003
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Physical Chemistry. A
ISSN
1089-5639
e-ISSN
—
Volume of the periodical
107
Issue of the periodical within the volume
N/A
Country of publishing house
US - UNITED STATES
Number of pages
8
Pages from-to
7347-7354
UT code for WoS article
—
EID of the result in the Scopus database
—