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Rovibrational spectra of DCF3 in the 1000 cm1 region: The ?5 = 1 and ?6 = 2 levels revisited

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F11%3A00360621" target="_blank" >RIV/61388955:_____/11:00360621 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1016/j.jms.2011.03.016" target="_blank" >http://dx.doi.org/10.1016/j.jms.2011.03.016</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.jms.2011.03.016" target="_blank" >10.1016/j.jms.2011.03.016</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Rovibrational spectra of DCF3 in the 1000 cm1 region: The ?5 = 1 and ?6 = 2 levels revisited

  • Original language description

    The degenerate fundamental vibrational level v5 = 1 (975.51 cm1, E symmetry) and the overtone vibrational level v6 = 2 (1004.06/1005.98 cm1, A1 + E symmetry) were reinvestigated with inclusion of their inter-vibrational couplings: the anharmonic Fermi interaction (?K=0, ?t?lt=?l5+?l6=3), the second-order Coriolis resonance (?K=1, ?t?lt=1), and the second-order ?-resonance (?K=minus-or-plus sign2, ?t?lt=1). This required significant extension of assignments to high J and K rotational states where resonant crossings due to the latter two interactions occur. The newly assigned data from Fourier-transform IR spectroscopy were combined with rotational and laser-sideband rovibrational data pertaining to the v5 = 1 vibrational level, which were used already in a previous analysis, in a fully quantitative simultaneous fit.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2011

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Molecular Spectroscopy

  • ISSN

    0022-2852

  • e-ISSN

  • Volume of the periodical

    267

  • Issue of the periodical within the volume

    1

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    8

  • Pages from-to

    150-157

  • UT code for WoS article

    000291715800021

  • EID of the result in the Scopus database