Rotational and rovibrational spectroscopy of the v 8?=?1 and 2 vibrational states of CH3NC
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F11%3A00365981" target="_blank" >RIV/61388955:_____/11:00365981 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1080/00268976.2011.605775" target="_blank" >http://dx.doi.org/10.1080/00268976.2011.605775</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1080/00268976.2011.605775" target="_blank" >10.1080/00268976.2011.605775</a>
Alternative languages
Result language
angličtina
Original language name
Rotational and rovibrational spectroscopy of the v 8?=?1 and 2 vibrational states of CH3NC
Original language description
The lowest frequency vibration?rotation band ? 8, corresponding to the degenerate CNC bending vibration of methyl isocyanide (CH3NC) with band center at 267.3?cm1, was studied by FTIR spectroscopy between 215 and 320?cm1 and rotational spectroscopy in the range from 201 to 383?GHz in order to describe the vibration?rotation dynamics with the inclusion of all important anharmonic and vibration?rotation interactions. Assignments extended to higher-K rotational states in both vibration?rotation and rotational spectra reveal a resonance crossing with the v 8? =?2 overtone level due to a local anharmonic Fermi resonance. The simultaneous analysis of both types of data provides a fully quantitative reproduction of the experimental data as well as a preliminary characterization of the v 8?=?2 level.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Molecular Physics
ISSN
0026-8976
e-ISSN
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Volume of the periodical
109
Issue of the periodical within the volume
17
Country of publishing house
GB - UNITED KINGDOM
Number of pages
7
Pages from-to
2237-2243
UT code for WoS article
000296554100017
EID of the result in the Scopus database
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