All

What are you looking for?

All
Projects
Results
Organizations

Quick search

  • Projects supported by TA ČR
  • Excellent projects
  • Projects with the highest public support
  • Current projects

Smart search

  • That is how I find a specific +word
  • That is how I leave the -word out of the results
  • “That is how I can find the whole phrase”

Caging of Cl atoms from photodissociation of CF2Cl2 in clusters

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F14%3A00394141" target="_blank" >RIV/61388955:_____/14:00394141 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1039/C3CP51926K" target="_blank" >http://dx.doi.org/10.1039/C3CP51926K</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1039/C3CP51926K" target="_blank" >10.1039/C3CP51926K</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Caging of Cl atoms from photodissociation of CF2Cl2 in clusters

  • Original language description

    We investigate the photodissociation dynamics of freon CF2Cl2 by velocity map imaging at 193 nm. The Cl fragment images are recorded in various expansion regimes corresponding to isolated molecules and molecules in rare gas clusters. The molecular kinetic energy distributions are dominated by a peak at Ekin(Cl) 0.97 eV corresponding to the direct C?Cl bond dissociation but they also reveal features at lower kinetic energies. Possible mechanisms leading to these slow Cl atoms are discussed. The photodissociation in clusters is investigated in two regimes: (i) small Ar clusters with the CF2Cl2 molecule embedded in approximately one solvation Ar layer; (ii) large Xen, [n with combining overline] 100?500, clusters with embedded CF2Cl2 molecules. In the former clusters we observe caging yielding the Cl fragments with zero kinetic energy and direct exit resulting in fragments with the kinetic energies corresponding to the fragments from isolated molecules. In the latter case (ii) only the ca

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GAP208%2F11%2F0161" target="_blank" >GAP208/11/0161: Dynamicss of Solvated Electrons in Molecular Clusters: Experimental and Theoretical Approach</a><br>

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2014

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Physical Chemistry Chemical Physics

  • ISSN

    1463-9076

  • e-ISSN

  • Volume of the periodical

    16

  • Issue of the periodical within the volume

    2

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    9

  • Pages from-to

    421-429

  • UT code for WoS article

    000327888100006

  • EID of the result in the Scopus database