Electrochemical Reduction of FOX-7 in Aprotic Solvent Accompanied by Formation of a Radical with Alternating Line-width Effect
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F15%3A00444483" target="_blank" >RIV/61388955:_____/15:00444483 - isvavai.cz</a>
Result on the web
—
DOI - Digital Object Identifier
—
Alternative languages
Result language
angličtina
Original language name
Electrochemical Reduction of FOX-7 in Aprotic Solvent Accompanied by Formation of a Radical with Alternating Line-width Effect
Original language description
Different structures of FOX-7 in various solutions play a crucial role in the mechanism of its electrochemical reduction. In aprotic solvent the irreversible four-electron, four-proton reduction of one nitro group proceeds according to the autoprotonation mechanism. The zwitterionic form of FOX-7 serves as a source of protons. The two-step reduction is accompanied by an adsorption step in dependence on used solvent and material of electrode. The in situ spectroelectrochemical measurements revealed formation of a dianion radical intermediate with alternating line-width effect. The intramolecular dynamic processes were described by temperature dependent in situ ESR measurement.
Czech name
—
Czech description
—
Classification
Type
D - Article in proceedings
CEP classification
CG - Electrochemistry
OECD FORD branch
—
Result continuities
Project
<a href="/en/project/GA13-21704S" target="_blank" >GA13-21704S: Electrochemically active calix[4]arenes and their use for preparation of new receptors and (bio)sensors</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Article name in the collection
XXXV. Moderní elektrochemické metody. Sborník přednášek mezinárodní odborné konference
ISBN
978-80-905221-3-8
ISSN
—
e-ISSN
—
Number of pages
5
Pages from-to
228-232
Publisher name
Srsenová Lenka - Best Servis
Place of publication
Ústí nad Labem
Event location
Jetřichovice
Event date
May 18, 2015
Type of event by nationality
WRD - Celosvětová akce
UT code for WoS article
000358792900051