Electron interactions with Bis(pentamethylcyclopentadienyl) titanium(IV) dichloride and difluoride
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F18%3A00492267" target="_blank" >RIV/61388955:_____/18:00492267 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1140/epjd/e2018-80794-6" target="_blank" >http://dx.doi.org/10.1140/epjd/e2018-80794-6</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1140/epjd/e2018-80794-6" target="_blank" >10.1140/epjd/e2018-80794-6</a>
Alternative languages
Result language
angličtina
Original language name
Electron interactions with Bis(pentamethylcyclopentadienyl) titanium(IV) dichloride and difluoride
Original language description
We present a combined experimental and theoretical study of the interaction of electrons with Bis(pentamethylcyclopentadienyl)titanium(IV) dichloride (Cp2*TiCl2) and difluoride (Cp2*TiF2). We report the experimental measurements of partial cross sections for the dissociative electron attachment (DEA) and the electron ionization (EI) mass spectra of isolated molecules. Estimates of the absolute cross sections are done on the basis of cross-calibration in the case of DEA and on the basis of binary-encounter-Bethe calculation in the case of EI. EI of both molecules is similar, concerning cross section amplitude and fragmentation pattern. DEA is different: DEA to Cp2*TiF2primarily results in the formation of stable parent anion, while DEA to Cp2*TiCl2results in the strong fragmentation, primarily into Cl−anion. Possible use of the molecules as the model species for studies of DEA efficiency in postirradiation chemistry is discussed. Graphical abstract: [Figure not available: see fulltext.].
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
<a href="/en/project/GJ16-10995Y" target="_blank" >GJ16-10995Y: Reactions of organometallic complexes relevant for the ion beam cancer therapy</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2018
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
European Physical Journal D
ISSN
1434-6060
e-ISSN
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Volume of the periodical
72
Issue of the periodical within the volume
6
Country of publishing house
DE - GERMANY
Number of pages
6
Pages from-to
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UT code for WoS article
000436369700003
EID of the result in the Scopus database
2-s2.0-85048870537