Electrochemically triggered degradation of energetic material FOX-7 (2,2-dinitroethene-1,1-diamine) Structural, redox, and spectrometric characterization in solution

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F20%3A00522228" target="_blank" >RIV/61388955:_____/20:00522228 - isvavai.cz</a>
Result on the web
<a href="http://hdl.handle.net/11104/0306751" target="_blank" >http://hdl.handle.net/11104/0306751</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/poc.4046" target="_blank" >10.1002/poc.4046</a>

Result language
angličtina
Original language name
Electrochemically triggered degradation of energetic material FOX-7 (2,2-dinitroethene-1,1-diamine) Structural, redox, and spectrometric characterization in solution
Original language description
This work represents systemati11c electrochemical and spectrometric characterization of 2,2-dinitroethene-1,1-diamine, the energetic material (explosive) known as FOX-7, in aqueous as well as various organic solvents. On the basis of results obtained from combination of electrochemistry with ultraviolet-visible-near-infrared (UV-vis-NIR), infrared (IR), nuclear magnetic resonance (NMR), electron paramagnetic resonance (EPR), mass spectrometry (MS), gas chromatography (GC), and high-performance liquid chromatography (HPLC) methods, the actual structure of FOX-7 in various media was revealed, its reducibility was described, and radical intermediates as well as most of the products were intercepted and identified. Instead of expected cathodic reduction of the dinitro derivative, electrochemically initiated spontaneous degradation accompanied by release of gaseous products in all media was found.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)

Project
<a href="/en/project/GA18-12150S" target="_blank" >GA18-12150S: Synthesis and characterization of semiconducting supramolecules of novel type and their use in preparation of organic transistors (OFETs)</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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