Metallation of a gold(i) metalloligand with P,C-bridging phosphinoferrocenyl groups enables the construction of defined multimetallic arrays
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F22%3A00556899" target="_blank" >RIV/61388955:_____/22:00556899 - isvavai.cz</a>
Alternative codes found
RIV/00216208:11310/22:10443827
Result on the web
<a href="http://hdl.handle.net/11104/0331016" target="_blank" >http://hdl.handle.net/11104/0331016</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/d2dt00850e" target="_blank" >10.1039/d2dt00850e</a>
Alternative languages
Result language
angličtina
Original language name
Metallation of a gold(i) metalloligand with P,C-bridging phosphinoferrocenyl groups enables the construction of defined multimetallic arrays
Original language description
The reactions of the gold(i) metalloligand [Au-2{mu(P,C)-Ph(2)Pfc}(2)], where fc stands for ferrocene-1,1 '-diyl, with bare or ligand-stabilised group 11 metal ions open access to diverse oligometallic clusters stabilised by Au-Au, Au-Ag and Au-Cu interactions. These capping reactions and the unique structures of the products stem from unparalleled properties of the bridging ferrocene groups, namely their structural flexibility and electron-rich nature, which enable accommodating the capping moieties and supporting ligands and facilitate electrophilic metalation, respectively. While the Au+ and Ag+ ions behave similarly, capping reactions with Cu+ proceed differently, with an accentuated role of the counter ions and other ligands in the system. Such behaviour reflects the relative strengths of the Au-M metallophilic interaction (M = Au, Ag and Cu), among which the Au-Cu interactions are the weakest, as confirmed by DFT calculations.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
—
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2022
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Dalton Transactions
ISSN
1477-9226
e-ISSN
1477-9234
Volume of the periodical
51
Issue of the periodical within the volume
16
Country of publishing house
GB - UNITED KINGDOM
Number of pages
6
Pages from-to
6410-6415
UT code for WoS article
000779731500001
EID of the result in the Scopus database
2-s2.0-85128799956