Electron attachment to CH3COCl molecule and clusters
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F25%3A00637336" target="_blank" >RIV/61388955:_____/25:00637336 - isvavai.cz</a>
Alternative codes found
RIV/60461373:22340/25:43931824
Result on the web
<a href="https://hdl.handle.net/11104/0368239" target="_blank" >https://hdl.handle.net/11104/0368239</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/D5RA02679B" target="_blank" >10.1039/D5RA02679B</a>
Alternative languages
Result language
angličtina
Original language name
Electron attachment to CH3COCl molecule and clusters
Original language description
We investigate the electron attachment of acetyl chloride CH3COCl (AC) molecules and clusters in a molecular beam experiment and by extensive theoretical calculations. The main product of dissociative electron attachment (DEA) to the AC molecule is Cl−, which leads to the main (AC)nCl− series in clusters. The weaker ion series identified in the cluster mass spectra correspond to (AC)nHCl2− and hydrogen abstraction fragments [(AC)n–H]−, in full agreement with calculated energetics. We compare the present results for AC with previously studied trifluoroacetyl chloride CF3COCl (TFAC) and trichloroacetic acid CCl3COOH (TCA) molecules and clusters. DEA of the three isolated molecules results in the main fragment Cl−. However, the electron attachment to their clusters produces distinctly different cluster ions. This demonstrates that the outcomes of reactions of electrons with molecules in an environment cannot easily be predicted from the DEA of isolated molecules, and the solvent plays a key role in the process.n
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2025
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
RSC Advances
ISSN
2046-2069
e-ISSN
2046-2069
Volume of the periodical
15
Issue of the periodical within the volume
29
Country of publishing house
GB - UNITED KINGDOM
Number of pages
11
Pages from-to
23983-23993
UT code for WoS article
001525119400001
EID of the result in the Scopus database
2-s2.0-105010517527