Radical polymerization of 1-alkenes catalyzed by lithium salts of carboranes

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F11%3A00359127" target="_blank" >RIV/61388963:_____/11:00359127 - isvavai.cz</a>
Alternative codes found
RIV/61389013:_____/11:00359127
Result on the web
<a href="http://dx.doi.org/10.1002/pola.24629" target="_blank" >http://dx.doi.org/10.1002/pola.24629</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/pola.24629" target="_blank" >10.1002/pola.24629</a>

Result language
angličtina
Original language name
Radical polymerization of 1-alkenes catalyzed by lithium salts of carboranes
Original language description
Radical polymerization of selected 1-alkenes, (1-hexene, 1-octene and 2-methyl-1-heptene), initiated with classical radical initiators and catalyzed by lithium salts of selected carboranes was studied. In accordance with recently published results it wasfound that the use of radical initiators under catalysis by "naked'' lithium cation of carboranes promotes the radical polymerization of 1-alkenes, otherwise nonpolymerizable by the radical mechanism. However, although in our experiments relatively highmonomers conversions are reached for some of the thermal initiators used, only low-molecular-weight oligomers with M-n < 1000 are formed, regardless of the initiator and carborane anion used.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CD - Macromolecular chemistry
OECD FORD branch
—

Project
<a href="/en/project/ME09001" target="_blank" >ME09001: Radical polymerization of 1-alkenes promoted with Li salts of monocarbadodecaborates</a><br>
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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