Environmental fate of sulfidated nZVI particles: the interplay of nanoparticle corrosion and toxicity during aging
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388971%3A_____%2F20%3A00534781" target="_blank" >RIV/61388971:_____/20:00534781 - isvavai.cz</a>
Alternative codes found
RIV/61989592:15310/20:73603842 RIV/46747885:24620/20:00007772 RIV/00216208:11310/20:10414064
Result on the web
<a href="https://pubs.rsc.org/en/content/articlelanding/2020/EN/D0EN00075B#!divAbstract" target="_blank" >https://pubs.rsc.org/en/content/articlelanding/2020/EN/D0EN00075B#!divAbstract</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/d0en00075b" target="_blank" >10.1039/d0en00075b</a>
Alternative languages
Result language
angličtina
Original language name
Environmental fate of sulfidated nZVI particles: the interplay of nanoparticle corrosion and toxicity during aging
Original language description
Nanomaterials have attracted research attention due to their unique properties, which have also made them increasingly useful for various applications, including remediation technologies. In this work, we tried to explore the aging phenomenon of several newly developed nanoscale zero-valent iron (nZVI) particles containing 0.25, 1, and 5% sulfur and to monitor the possible toxicity changes related to the nZVI particles before and during the aging period. We used several relevant techniques for monitoring nZVI aging, including transmission electron microscopy, X-ray powder diffraction, and particle size analysis. The toxicity of the nZVI particles was monitored using a new oxidative stress assay based on lipid peroxidation, a simple bacterial cultivation test. A test using activated sludge respiration and phospholipid fatty acid analysis of microbial populations was also employed. The results of the material analyses showed that the sulfidated nZVI particles were more stable than bare nZVI particles in terms of Fe(0)content and particle diameter. The stability was more pronounced with the increasing content of sulfur in the nanoparticles, the content of alpha-Fe was only 35.3% in the nZVI particles compared with 78.6% in the 5% sulfur-doped nanoparticles after 60 days of aging. The results of the oxidative stress assay revealed that the toxicity was also lower with increasing sulfur content, nevertheless, the oxidative stress marker increased substantially after 7 days of aging, reaching a similar level to that caused by bare nZVI in some cases. Other results showed that even incubation in media used for the respective tests caused extensive aging, therefore, this information must be considered before the selection of toxicity assays for nanomaterial evaluation.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10511 - Environmental sciences (social aspects to be 5.7)
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Environmental Science-Nano
ISSN
2051-8153
e-ISSN
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Volume of the periodical
7
Issue of the periodical within the volume
6
Country of publishing house
GB - UNITED KINGDOM
Number of pages
13
Pages from-to
1794-1806
UT code for WoS article
000545480500015
EID of the result in the Scopus database
2-s2.0-85087938848