Two new macropolyhedral chalcogenaboranes: S2B16H18 and SeB16H18

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F22%3A00561020" target="_blank" >RIV/61388980:_____/22:00561020 - isvavai.cz</a>
Result on the web
<a href="https://doi.org/10.1016/j.ica.2022.121148" target="_blank" >https://doi.org/10.1016/j.ica.2022.121148</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.ica.2022.121148" target="_blank" >10.1016/j.ica.2022.121148</a>

Result language
angličtina
Original language name
Two new macropolyhedral chalcogenaboranes: S2B16H18 and SeB16H18
Original language description
The dithiaborane S2B16H18 (1) is a minor product isolated from the preparation of S2B17H17. It is structurally closely related both to the known compound iso-S2B16H16 (3) and to the new macropolyhedral selenaborarane SeB16H18 (2), which is isolated from the thermal decomposition of the [SeB18H19]− anion. Both new compounds 1 and 2 are therefore produced by boron loss from higher chalcogenaborane compounds. The single-crystal X-ray structures and the boron-11 NMR shielding characteristics show the close similarities of all three compounds.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry

Project
<a href="/en/project/LM2018124" target="_blank" >LM2018124: Nanomaterials and Nanotechnologies for Environment Protection and Sustainable Future</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2022
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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