“Activated Borane” - A Porous Borane Cluster Network as an Effective Adsorbent for Removing Organic Pollutants
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F22%3A00562669" target="_blank" >RIV/61388980:_____/22:00562669 - isvavai.cz</a>
Alternative codes found
RIV/61389013:_____/22:00562669 RIV/44555601:13520/22:43897193
Result on the web
<a href="https://doi.org/10.1002/chem.202201885" target="_blank" >https://doi.org/10.1002/chem.202201885</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/chem.202201885" target="_blank" >10.1002/chem.202201885</a>
Alternative languages
Result language
angličtina
Original language name
“Activated Borane” - A Porous Borane Cluster Network as an Effective Adsorbent for Removing Organic Pollutants
Original language description
The unprecedented co-thermolysis of decaborane(14) (nido-B10H14) and toluene results in a novel porous material (that we have named “activated borane”) containing micropores between 1.0 and 1.5 nm in diameter and a specific surface area of 774 m(2) g(-1) (Ar, 87 K) that is thermally stable up to 1000 degrees C. Solid state H-1, B-11 and C-13 MAS NMR, UV-vis and IR spectroscopies suggest an amorphous structure of borane clusters interconnected by toluene moieties in a ratio of about three toluene molecules for every borane cluster. In addition, the structure contains Lewis-acidic tri-coordinated boron sites giving it some unique properties. Activated borane displays high sorption capacity for pollutants such as sulfamethoxazole, tramadol, diclofenac and bisphenol A that exceed the capacity of commercially-available activated carbon. The consistency in properties for each batch made, and the ease of its synthesis, make activated borane a promising porous material worthy of broad attention.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2022
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Chemistry - A European Journal
ISSN
0947-6539
e-ISSN
1521-3765
Volume of the periodical
28
Issue of the periodical within the volume
67
Country of publishing house
DE - GERMANY
Number of pages
8
Pages from-to
e202201885
UT code for WoS article
000864929600001
EID of the result in the Scopus database
2-s2.0-85139520580