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Microstructural changes of amorphous Mo–B–C coatings upon thermal annealing

Result description

Several amorphous Mo–B–C coatings with wide range of compositions were subjected to thermal annealing to a final temperature of 1000 °C in UHV conditions. The nature of the induced recrystallization depended mostly on the Mo content in the coating. A higher Mo content resulted in a nanocrystalline Mo2C phase, a lower Mo content in a nanocrystalline Mo2BC phase and Mo content in-between resulted only in a near-amorphous microstructure. In all cases, the hardness and effective elastic modulus increased significantly after annealing up to values of ∼29 GPa and 500 GPa, respectively. The cobalt diffusion from the WC-Co substrates affected the lower parts of coatings forming a MoCoB interface.

Keywords

magnetron sputteringMo2BCMo2C

The result's identifiers

Alternative languages

  • Result language

    angličtina

  • Original language name

    Microstructural changes of amorphous Mo–B–C coatings upon thermal annealing

  • Original language description

    Several amorphous Mo–B–C coatings with wide range of compositions were subjected to thermal annealing to a final temperature of 1000 °C in UHV conditions. The nature of the induced recrystallization depended mostly on the Mo content in the coating. A higher Mo content resulted in a nanocrystalline Mo2C phase, a lower Mo content in a nanocrystalline Mo2BC phase and Mo content in-between resulted only in a near-amorphous microstructure. In all cases, the hardness and effective elastic modulus increased significantly after annealing up to values of ∼29 GPa and 500 GPa, respectively. The cobalt diffusion from the WC-Co substrates affected the lower parts of coatings forming a MoCoB interface.

  • Czech name

  • Czech description

Classification

  • Type

    JSC - Article in a specialist periodical, which is included in the SCOPUS database

  • CEP classification

  • OECD FORD branch

    10302 - Condensed matter physics (including formerly solid state physics, supercond.)

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2019

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Surface and Coatings Technology

  • ISSN

    0257-8972

  • e-ISSN

  • Volume of the periodical

    379

  • Issue of the periodical within the volume

    DEC

  • Country of publishing house

    CH - SWITZERLAND

  • Number of pages

    7

  • Pages from-to

    125052

  • UT code for WoS article

    000498752500008

  • EID of the result in the Scopus database

    2-s2.0-85073072737

Basic information

Result type

JSC - Article in a specialist periodical, which is included in the SCOPUS database

JSC

OECD FORD

Condensed matter physics (including formerly solid state physics, supercond.)

Year of implementation

2019