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New copolymer brushes for label-free affinity biosensors

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F15%3A00462552" target="_blank" >RIV/61389013:_____/15:00462552 - isvavai.cz</a>

  • Alternative codes found

    RIV/67985882:_____/15:00462552

  • Result on the web

    <a href="http://dx.doi.org/10.1109/ICSENS.2015.7370596" target="_blank" >http://dx.doi.org/10.1109/ICSENS.2015.7370596</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1109/ICSENS.2015.7370596" target="_blank" >10.1109/ICSENS.2015.7370596</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    New copolymer brushes for label-free affinity biosensors

  • Original language description

    Brushes of poly(HPMA-co-CBMAA) copolymer with an adjustable content of functional carboxybetaine (CBMAA) monomer units were grafted from surface of SPR chips using surface initiated atom transfer radical polymerization (SI ATRP). Compared to brushes of of poly(carboxybetaine) (polyCBAA), which so far have provided the best antifouling biorecognition layers, the new brushes were more resistant to undiluted human blood plasma, milk, and crude food extracts, particularly after the covalent attachment of bioreceptors. The incorporation of a selected number of functional CBMAA units in poly(hydroxypropyl methacrylamide) (poly(HPMA)) allowed us to reach ultralow fouling properties better than that of polyCBAA. A typical food-born pathogen bacteria, E.coli O157:H7, was detected in crude extracts of hamburger and lettuce using SPR biosensor coated by biorecognition layers composed of poly(HPMA-co-CBMAA) brushes with covalently attached anti-E. coli antibodies. The SPR biosensor with attached surface antigen of hepatitis B virus HBsAg was used to detect the presence of anti-HBsAg antibodies as biomarkers of hepatitis B infection in standard clinical samples of sera taken from several individuals. The new ultralow fouling biorecognition layers open a feasible way to label-free biosensors capable of in real time detecting analytes in real samples of complex biological media tested for medical diagnostics or food control.

  • Czech name

  • Czech description

Classification

  • Type

    D - Article in proceedings

  • CEP classification

    BO - Biophysics

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GBP205%2F12%2FG118" target="_blank" >GBP205/12/G118: Nanobiophotonics for future health care</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2015

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Article name in the collection

    IEEE SENSORS 2015

  • ISBN

    978-1-4799-8203-5

  • ISSN

    1930-0395

  • e-ISSN

  • Number of pages

    4

  • Pages from-to

    1626-1629

  • Publisher name

    IEEE

  • Place of publication

    New York

  • Event location

    Busan

  • Event date

    Nov 1, 2015

  • Type of event by nationality

    WRD - Celosvětová akce

  • UT code for WoS article

    000380440800424