One-dimensional complex {[Cu(medpt)][Ag(CN)2]2}n

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989100%3A27640%2F09%3A00021841" target="_blank" >RIV/61989100:27640/09:00021841 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

One-dimensional complex {[Cu(medpt)][Ag(CN)2]2}n

Original language description

The novel compound, {[Cu(medpt)][Ag(CN)2]2}n (medpt = N,N-bis-(3-aminopropyl)methylamine), was isolated from a reaction mixture containing Cu(ClO4)2 6H2O, medpt and K[Ag(CN)2]. The new complex was characterized by IR spectroscopy, magnetochemical studiesand by X-ray single crystal diffraction. The structure contains [Cu(medpt)]2+ units being bridged by [Ag(CN)2]- units resulting in chains of the composition [-CN-Cu(medpt)-NC-Ag-]n, and dicyanoargentate anions. Ag-Ag interactions link free [Ag(CN)2]- anions to the chain. The copper(II) atom is five coordinated to two cyanide-nitrogen and three medpt-nitrogen atoms in a distorted square-pyramidal arrangement.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

JI - Composite materials

OECD FORD branch

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Project

<a href="/en/project/GA205%2F08%2F0869" target="_blank" >GA205/08/0869: Clay minerals as host matrices for functional nanostructures</a><br>

Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2009

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Acta Chimica Slovenica

ISSN

1318-0207

e-ISSN

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Volume of the periodical

56

Issue of the periodical within the volume

2

Country of publishing house

SK - SLOVAKIA

Number of pages

3

Pages from-to

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UT code for WoS article

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EID of the result in the Scopus database

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