One-dimensional Complex {[Cu(medpt)][Ag(CN)(2)](2)}(n) (medpt = N,N-bis-(3-aminopropyl)methylamine)

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F09%3A00010170" target="_blank" >RIV/61989592:15310/09:00010170 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

One-dimensional Complex {[Cu(medpt)][Ag(CN)(2)](2)}(n) (medpt = N,N-bis-(3-aminopropyl)methylamine)

Original language description

The novel compound, {[Cu(medpt)][Ag(CN)(2)](2)}(n) (medpt = N,N-bis-(3-aminopropyl)methylamine), was isolated from a reaction mixture containing Cu(ClO4)(2) center dot 6H(2)O, medpt and K[Ag(CN)(2)]. The new complex was characterized by IR spectroscopy,magnetochemical studies and by X-ray single crystal diffraction. The structure contains [Cu(medpt)](2+) units being bridged by [Ag(CN)(2)](-) units resulting in chains of the composition [-mu-CN-Cu(medpt)-mu-NC-Ag-](n), and dicyanoargentate anions. Ag center dot center dot center dot Ag interactions link free [Ag(CN)(2)](-) anions to the chain. The copper(II) atom is five coordinated to two cyanide-nitrogen and three medpt-nitrogen atoms in a distorted square-pyramidal arrangement.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

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Continuities

S - Specificky vyzkum na vysokych skolach

Publication year

2009

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Acta Chimica Slovenica

ISSN

1318-0207

e-ISSN

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Volume of the periodical

56

Issue of the periodical within the volume

2

Country of publishing house

SI - SLOVENIA

Number of pages

4

Pages from-to

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UT code for WoS article

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EID of the result in the Scopus database

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