Preparation, physicochemical properties and biological activity of copper(II) complexes with 6-(2-chlorbenzylamino)purine (HL1) or 6-(3-chlorbenzylamino)purine (HL2). The single-crystal X-ray structure of [Cu(H(+)L2]2Cl3]Cl.2H2O
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F01%3A00001268" target="_blank" >RIV/61989592:15310/01:00001268 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Preparation, physicochemical properties and biological activity of copper(II) complexes with 6-(2-chlorbenzylamino)purine (HL1) or 6-(3-chlorbenzylamino)purine (HL2). The single-crystal X-ray structure of [Cu(H(+)L2]2Cl3]Cl.2H2O
Original language description
A series of mononuclear Cu(II), Pd(II) and Pt(II) complexes with selected 6-benzylaminopurine derivatives, namely 6-(2-hydroxybenzylamino)purine 2OHBAP, 6-(3-fluorobenzylamino)purine 3FBAP, 2-(3-hydroxypropylamino)-6-benzylamino-9-isopropylpurine BOH and2-(2-hydroxyethylamino)-6-benzylamino-9-metylpurine OLO, has been synthesized and characterized by elemental analysis, electronic, infrared and mass (FAB+, ESI+) spectral data, magnetic susceptibility and molar conductivity data. On the basis of data resulting mainly from a single crystal X-ray analysis, a composition of the prepared complexes is following: [CuCl3(2OHBAP+)2]Cl.2H2O, [CuCl3(3FBAP+)2]Cl.H2O, [PdCl3(BOH+)].H2O, [PdCl3(OLO+)].H2O, [PtCl3(BOH+)].H2O, [PtCl3(OLO+)].H2O. Cytotoxic activity ofthe complexes as well as the starting compounds was determined by a calcein AM assay on various human tumor cell lines.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2001
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Inorganic Biochemistry
ISSN
0162-0134
e-ISSN
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Volume of the periodical
84
Issue of the periodical within the volume
N
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
10
Pages from-to
23-32
UT code for WoS article
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EID of the result in the Scopus database
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