Coordination Chemistry of Conformation-Flexible 1,2,3,4,5,6-Cyclohexanehexacarboxylate: Trapping Various Conformations in Metal-Organic Frameworks

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F08%3A00009951" target="_blank" >RIV/61989592:15310/08:00009951 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Coordination Chemistry of Conformation-Flexible 1,2,3,4,5,6-Cyclohexanehexacarboxylate: Trapping Various Conformations in Metal-Organic Frameworks

Original language description

To study the conformations of 1,2,3,4,5,6-cyclohexanehexacarboxylic acid (H6L), eleven new coordination polymers have been isolated from hydrothermal reactions of different metal salts with 1e,2a,3e,4a,5e,6a-cyclohexanehexacarboxylic acid (3e+3a, H6LI) and characterized. They are [Cd12(6-LII)(10-LII)3(-H2O)6(H2O)6]16.5 H2O (1), Na12[Cd6(6-LII)(6-LIII)3]27 H2O (2), [Cd3(13-LII)(-H2O)] (3), [Cd3(6-LIII)(2,2-bpy)3(H2O)3]2 H2O (4), [Cd4(4-LVI)2(4,4-Hbpy)4(4,4-bpy)2(H2O)4]9.5 H2O (5), [Cd2(6-LII)(4,4-Hbpy)2(H2O)10]5 H2O (6), [Cd3(11-LVI)(H2O)3] (7), [M3(9-LII)(H2O)6] (M=Mn (8), Fe (9), and Ni (10)), and [Ni4(OH)2(10-LII)(4,4-bpy)(H2O)4]6 H2O (11). Three new conformations of 1,2,3,4,5,6-cyclohexanehexacarboxylate, 6e (LII), 4e+2a (LIII) and 5e+1a (LVI), havebeen derived from the conformational conversions of LI and trapped in these complexes by controlling the conditions of the hydrothermal systems. Complexes 1 and 2 have three-dimensional (3D) coordination frameworks with nanoscale cages a

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

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Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)<br>S - Specificky vyzkum na vysokych skolach

Publication year

2008

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Chemistry - A European Journal

ISSN

0947-6539

e-ISSN

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Volume of the periodical

14

Issue of the periodical within the volume

24

Country of publishing house

DE - GERMANY

Number of pages

18

Pages from-to

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UT code for WoS article

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EID of the result in the Scopus database

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