Syntheses and magnetic properties of trinuclear trithiocyanurato-bridged manganese(II) complexes involving bidentate aromatic N-donor heterocycles
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F10%3A10213081" target="_blank" >RIV/61989592:15310/10:10213081 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Syntheses and magnetic properties of trinuclear trithiocyanurato-bridged manganese(II) complexes involving bidentate aromatic N-donor heterocycles
Original language description
Trinuclear manganese(II) complexes of the compositions [Mn3(phen)6(ttc)](ClO4)3 (1), [Mn3(dmbpy)6(ttc)](ClO4)3?2H2O (2) and [Mn3(bpy)6(ttc)](ClO4)3?3H2O (3), where phen=1,10-phenanthroline, dmbpy=4,4?-dimethyl-2,2?-bipyridine, bpy=2,2?-bipyridine and H3ttc=trithiocyanuric acid (2,4,6-trimercapto-1,3,5-triazine), were prepared and characterized by elemental analysis, FTIR and Raman spectroscopies, MALDITOF mass spectrometry, magnetic and conductivity measurements. The magnetic analysis incorporating simultaneous fitting of the temperature dependence and the field dependence of the magnetization using the isosceles triangle spin Hamiltonian model revealed a weak antiferromagnetic exchange within the trinuclear units.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2010
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Inorganic Chemistry Communications
ISSN
1387-7003
e-ISSN
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Volume of the periodical
13
Issue of the periodical within the volume
6
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
4
Pages from-to
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UT code for WoS article
000279136700023
EID of the result in the Scopus database
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