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Syntheses and magnetic properties of trinuclear trithiocyanurato-bridged manganese(II) complexes involving bidentate aromatic N-donor heterocycles

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F10%3A10213081" target="_blank" >RIV/61989592:15310/10:10213081 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Syntheses and magnetic properties of trinuclear trithiocyanurato-bridged manganese(II) complexes involving bidentate aromatic N-donor heterocycles

  • Original language description

    Trinuclear manganese(II) complexes of the compositions [Mn3(phen)6(ttc)](ClO4)3 (1), [Mn3(dmbpy)6(ttc)](ClO4)3?2H2O (2) and [Mn3(bpy)6(ttc)](ClO4)3?3H2O (3), where phen=1,10-phenanthroline, dmbpy=4,4?-dimethyl-2,2?-bipyridine, bpy=2,2?-bipyridine and H3ttc=trithiocyanuric acid (2,4,6-trimercapto-1,3,5-triazine), were prepared and characterized by elemental analysis, FTIR and Raman spectroscopies, MALDITOF mass spectrometry, magnetic and conductivity measurements. The magnetic analysis incorporating simultaneous fitting of the temperature dependence and the field dependence of the magnetization using the isosceles triangle spin Hamiltonian model revealed a weak antiferromagnetic exchange within the trinuclear units.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CA - Inorganic chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2010

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Inorganic Chemistry Communications

  • ISSN

    1387-7003

  • e-ISSN

  • Volume of the periodical

    13

  • Issue of the periodical within the volume

    6

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    4

  • Pages from-to

  • UT code for WoS article

    000279136700023

  • EID of the result in the Scopus database