X-ray structures of heteroleptic zinc(II) complexes involving combinations of O,O?-dialkyldithiophosphato and bidentate N-donor ligands
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F14%3A33153134" target="_blank" >RIV/61989592:15310/14:33153134 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1515/zkri-2014-1736" target="_blank" >http://dx.doi.org/10.1515/zkri-2014-1736</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1515/zkri-2014-1736" target="_blank" >10.1515/zkri-2014-1736</a>
Alternative languages
Result language
angličtina
Original language name
X-ray structures of heteroleptic zinc(II) complexes involving combinations of O,O?-dialkyldithiophosphato and bidentate N-donor ligands
Original language description
The detailed X-ray structural elucidation of reaction products of a zinc(II) salt with O,O?-dialkyldithiophosphate and nitrogen-containing heterocycles (N-N = 1,10-phenanthroline (phen) or 2,2?-bipyridine (bpy)) has been performed. Surprisingly, togetherwith [Zn(S2P(OR)2)2(N-N)] compounds, also ionic-type complexes having the formula of [Zn(N-N)3](S2P(OR)2)2 have been obtained using the same molar ratios of the reactants. The prepared complexes have been characterized by elemental analysis and single-crystal X-ray analysis. The crystallographic analysis showed that the bond lengths and bite angles of the prepared complexes are in good agreement with those of similar compounds. The crystal packing of described complexes is formed via pí-pí stacking interactions and/or C-H???S non-covalent contacts.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
S - Specificky vyzkum na vysokych skolach
Others
Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Zeitschrift für Kristallographie - Crystalline Materials
ISSN
2196-7105
e-ISSN
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Volume of the periodical
229
Issue of the periodical within the volume
7
Country of publishing house
DE - GERMANY
Number of pages
6
Pages from-to
537-542
UT code for WoS article
000340864000007
EID of the result in the Scopus database
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