Half-sandwich complexes of ruthenium, osmium, rhodium and iridium with DL-methionine or S-methyl-L-cysteine: a solid state and solution equilibrium study

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F15%3A33155834" target="_blank" >RIV/61989592:15310/15:33155834 - isvavai.cz</a>

Result on the web

<a href="http://pubs.rsc.org/en/content/articlepdf/2015/ra/c4ra15649h" target="_blank" >http://pubs.rsc.org/en/content/articlepdf/2015/ra/c4ra15649h</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1039/c4ra15649h" target="_blank" >10.1039/c4ra15649h</a>

Result language

angličtina

Original language name

Half-sandwich complexes of ruthenium, osmium, rhodium and iridium with DL-methionine or S-methyl-L-cysteine: a solid state and solution equilibrium study

Original language description

[(?6-p-cym)Ru(H2O)3]2+ with the thioether ligands dl-methionine (H2met+) or S-methyl-l-cysteine (H2mecys+) was studied with the combined use of pH-potentiometry, NMR and mass spectrometry in aqueous solution. Both ligands were found to form stable [(?6-p-cym)RuA]+ complexes with [S, NH2, COO-] coordination of the amino acids over a wide pH-range. Compounds were also tested for their in vitro cytotoxicity using human-derived ovarian cancer lines (A2780) and showed no anti-proliferative activity in the concentration range (0-50 ?M) studied.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

BO - Biophysics

OECD FORD branch

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Project

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Continuities

S - Specificky vyzkum na vysokych skolach

Publication year

2015

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

RSC Advances (online)

ISSN

2046-2069

e-ISSN

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Volume of the periodical

5

Issue of the periodical within the volume

11

Country of publishing house

GB - UNITED KINGDOM

Number of pages

14

Pages from-to

8094-8107

UT code for WoS article

000347720900040

EID of the result in the Scopus database

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