Magnetic and structural properties of dinuclear singly bridged-phenoxido metal(II) complexes

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F15%3A33156311" target="_blank" >RIV/61989592:15310/15:33156311 - isvavai.cz</a>
Result on the web
<a href="http://pubs.rsc.org/en/content/articlepdf/2015/dt/c4dt03508a" target="_blank" >http://pubs.rsc.org/en/content/articlepdf/2015/dt/c4dt03508a</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c4dt03508a" target="_blank" >10.1039/c4dt03508a</a>

Result language
angličtina
Original language name
Magnetic and structural properties of dinuclear singly bridged-phenoxido metal(II) complexes
Original language description
The reaction of a methanolic solution containing the bi-compartmental phenolic ligand 2,6-bis[bis(2-pyridylmethyl) aminomethyl]-4-chlorophenol (LCl-OH) with MCl2.nH(2)O in the presence of NH4PF6 or NaClO4 afforded the dinuclear bridged-phenoxido dichlorido-metal(II) complexes [Co-2(mu-(LO)-O-Cl)(H2O)(2)Cl-2][ Co-2(mu-(LO)-O-Cl)(MeOH)(2)Cl-2](PF6)(2) (1), [Ni-2(mu-(LO)-O-Cl)(MeOH)(2)Cl-2]PF6 (2), [Ni-2(mu-(LO)-O-Cl)(MeOH)(H2O)Cl-2]ClO4.1.25H(2)O (3), [Cu-2(mu-(LO)-O-Cl)Cl-2] PF6.1/2MeOH (4) and [Zn-2(mu-(LO)-O-Cl)Cl-2]PF6.MeOH (5). The complexes were characterized by elemental microanalyses, conductivity measurements, IR and UV-Vis spectroscopy, mass spectrometry and single crystal X-ray crystallography. Each M(II) center within the dinuclear complex cations is octahedrally coordinated in complexes 1-3, and five-coordinated distorted square pyramidal in 4 and 5. Magnetic susceptibility measurements at variable temperature of the complexes 1-4 revealed weak to moderate antiferromagnetic
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
<a href="/en/project/LO1305" target="_blank" >LO1305: Development of the center of advanced technologies and materials</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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