Synthesis and characterization of nano-peanuts of lead(II) coordination polymer [Pb(qcnh)(NO3)2]n with ultrasonic assistance: A new precursor for the preparation of pure-phase nano-sized PbO
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F17%3A73584015" target="_blank" >RIV/61989592:15310/17:73584015 - isvavai.cz</a>
Result on the web
<a href="https://www.sciencedirect.com/science/article/pii/S1350417716301833" target="_blank" >https://www.sciencedirect.com/science/article/pii/S1350417716301833</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.ultsonch.2016.05.041" target="_blank" >10.1016/j.ultsonch.2016.05.041</a>
Alternative languages
Result language
angličtina
Original language name
Synthesis and characterization of nano-peanuts of lead(II) coordination polymer [Pb(qcnh)(NO3)2]n with ultrasonic assistance: A new precursor for the preparation of pure-phase nano-sized PbO
Original language description
A sonochemical method was used to synthesize nano-peanuts of a new lead(II) coordination 1D polymer, [Pb(qcnh)(NO3)2]n (1), where qcnh = 2-quinolincarbaldehyde nicotinohydrazide. The compound was characterized by scanning electron microscopy (SEM), elemental analysis, IR spectroscopy, thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), X-ray powder diffraction (XRD), and single crystal X-ray analysis. The X-ray structure revealed that the Pb(II) atom is coordinated by one oxygen and three nitrogen atoms from two qcnh ligands and five oxygen atoms from three nitrate ligands in an 8 + 1 fashion with a PbN3O6 donor set. One of the PdAN distances in the vicinity of the central atom is a bit longer (Pb1AN1 = 2.939(4) Å), which shows the effect of the 6s2 lone electron pair localized within the valence shell of the lead(II) atom.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Ultrasonics Sonochemistry
ISSN
1350-4177
e-ISSN
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Volume of the periodical
34
Issue of the periodical within the volume
JAN
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
7
Pages from-to
255-261
UT code for WoS article
000387626500030
EID of the result in the Scopus database
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