Fluorinated Epoxides. 6. Chemoselectivity in the Preparation of 2-[(Heptafluoroisopropyl)methyl]oxirane from Iodoacetate and Iodohydrin Precursors.
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F03%3A27030242" target="_blank" >RIV/67985858:_____/03:27030242 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Fluorinated Epoxides. 6. Chemoselectivity in the Preparation of 2-[(Heptafluoroisopropyl)methyl]oxirane from Iodoacetate and Iodohydrin Precursors.
Original language description
Fluorinated iodoacetate (CF3)(2)CFCH(2)CHICH(2)OAe (1) (prepared by radical addition of perfluoroisopropyl iodide to allyl acetate) and fluorinated iodohydrin (CF3)(2)CFCH2CHICH2OH (2) (prepared from 1) were converted to the corresponding perfluoroalkylated oxirane (CF3)(2)CFCH2CH(-O-)CH2 (3) in the yield of 62%. The chemoselectivity of the oxirane formation appeared to be strongly dependent on the starting compound 1 or 2 and solvent used. Byproducts (CF3)(2)CFCH=CHCH2OH (4) and (CF3)(2)CFCH=CHCH2OAc (5) can form a major part of the products in the formation of epoxide 3.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2003
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Fluorine Chemistry
ISSN
0022-1139
e-ISSN
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Volume of the periodical
121
Issue of the periodical within the volume
1
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
4
Pages from-to
101-104
UT code for WoS article
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EID of the result in the Scopus database
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