Edge Effects in Voltage-step Transient I. Ohmic Losses in 1D Approximation (revisited)
Result description
Ohmic potential drop between the working and reference electrodes plays an important role in the early stage of the voltage-step transient process. Non-linear effect of the ohmic drop on the transient currents has been calculated for large voltage steps,assuming reversible behavior (negligible surface overpotential) of a redox couple O + ne = R. This report extends an older study by Wein (1991). In particular, it adds a series of analytic approximations and gives more accurate numerical solving.
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The result's identifiers
Result code in IS VaVaI
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Edge Effects in Voltage-step Transient I. Ohmic Losses in 1D Approximation (revisited)
Original language description
Ohmic potential drop between the working and reference electrodes plays an important role in the early stage of the voltage-step transient process. Non-linear effect of the ohmic drop on the transient currents has been calculated for large voltage steps,assuming reversible behavior (negligible surface overpotential) of a redox couple O + ne = R. This report extends an older study by Wein (1991). In particular, it adds a series of analytic approximations and gives more accurate numerical solving.
Czech name
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Czech description
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Classification
Type
O - Miscellaneous
CEP classification
CI - Industrial chemistry and chemical engineering
OECD FORD branch
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Result continuities
Project
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2010
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Basic information
Result type
O - Miscellaneous
CEP
CI - Industrial chemistry and chemical engineering
Year of implementation
2010