Proton Detection of Carbon-Carbon Couplings in Symmetrical Molecules: Analytical Explanation, SYMONA Pulse Sequence.
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F19%3A00498678" target="_blank" >RIV/67985858:_____/19:00498678 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.jmr.2018.12.002" target="_blank" >http://dx.doi.org/10.1016/j.jmr.2018.12.002</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.jmr.2018.12.002" target="_blank" >10.1016/j.jmr.2018.12.002</a>
Alternative languages
Result language
angličtina
Original language name
Proton Detection of Carbon-Carbon Couplings in Symmetrical Molecules: Analytical Explanation, SYMONA Pulse Sequence.
Original language description
The approach to the measurement of one-bond indirect spin–spin coupling constants between equivalent nuclei was revisited. The analytical formulas for development of the density matrix of strongly coupled symmetrical HC-C0H0 spin systems were derived and the optimal duration of polarization delay in the original 2QHMBC pulse sequence is discussed. Based on the analytical formulas a new version of a robust indirect detection experiment, called SYMONA (SYmmetrical MOlecules Natural Abundance doublequantum experiment), was proposed for carbon–carbon coupling constants detection in symmetrical molecules. Additionally, application of the SYMONA experiment to more complicated spin systems than isolated HC-C0H0 is discussed.
Czech name
—
Czech description
—
Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
<a href="/en/project/GA15-12719S" target="_blank" >GA15-12719S: Electron density distribution in polycyclic aromatic compounds through experiments; liquid state vs. solid state</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2019
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Magnetic Resonance
ISSN
1090-7807
e-ISSN
—
Volume of the periodical
298
Issue of the periodical within the volume
JAN 2019
Country of publishing house
US - UNITED STATES
Number of pages
8
Pages from-to
107-114
UT code for WoS article
000457351000014
EID of the result in the Scopus database
2-s2.0-85058064381