Flavin-Helicene Amphiphilic Hybrids: Synthesis, Characterization, and Preparation of Surface-Supported Films.
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F21%3A00550035" target="_blank" >RIV/67985858:_____/21:00550035 - isvavai.cz</a>
Alternative codes found
RIV/60461373:22310/21:43923618 RIV/00216208:11310/21:10438713 RIV/61989592:15110/21:73608618 RIV/00216224:14310/21:00121930
Result on the web
<a href="http://hdl.handle.net/11104/0325892" target="_blank" >http://hdl.handle.net/11104/0325892</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/cplu.202100092" target="_blank" >10.1002/cplu.202100092</a>
Alternative languages
Result language
angličtina
Original language name
Flavin-Helicene Amphiphilic Hybrids: Synthesis, Characterization, and Preparation of Surface-Supported Films.
Original language description
This work reports on the preparation and structural characterization of flavo[7]helicene 1 (flavin-[7]helicene conjugate), which was subsequently characterized at the molecular level in either an aqueous environment or an organic phase, at the supramolecular level in the form of polymeric layers, and also embedded in a lipidic mesophase environment to study the resulting properties of such a hybrid relative to its parent molecules. The flavin benzo[g]pteridin-2,4-dione (isoalloxazine) was selected for conjugation because of its photoactivity and reversible redox behavior. Compound 1 was prepared from 2-nitroso[6]helicene and 6-methylamino-3-methyluracil, and characterized using common structural and spectroscopic tools: circular dichroism (CD), circularly polarized luminescence (CPL) spectroscopy, cyclic voltammetry (CV), and DFT quantum calculations. In addition, a methodology that allows the loading of 1 enantiomers into an internally nanostructured lipid (1-monoolein) matrix was developed.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10401 - Organic chemistry
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2021
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
ChemPlusChem
ISSN
2192-6506
e-ISSN
2192-6506
Volume of the periodical
86
Issue of the periodical within the volume
7
Country of publishing house
DE - GERMANY
Number of pages
9
Pages from-to
982-990
UT code for WoS article
000649190900001
EID of the result in the Scopus database
2-s2.0-85105680063