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Probing the Thermodynamics of Incorporation of N-6-methyl-dATP Opposite an Abasic Site, dCMP, and dTMP During Simulated DNA Synthesis by Differential Scanning Calorimetry

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68081707%3A_____%2F18%3A00501578" target="_blank" >RIV/68081707:_____/18:00501578 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1002/slct.201803565" target="_blank" >http://dx.doi.org/10.1002/slct.201803565</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1002/slct.201803565" target="_blank" >10.1002/slct.201803565</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Probing the Thermodynamics of Incorporation of N-6-methyl-dATP Opposite an Abasic Site, dCMP, and dTMP During Simulated DNA Synthesis by Differential Scanning Calorimetry

  • Original language description

    Previous reports indicated that when an abasic (apurinic/apyrimidinic, AP) site is bypassed by DNA polymerases, dATP is preferentially inserted. Here we evaluate, using differential scanning calorimetry, the thermodynamic changes associated with incorporation of N-6-methyl-dATP opposite an AP site, dCMP, and dTMP during simulated DNA polymerization. The results confirm that AP sites block DNA polymerases one nucleotide prior to the lesion. Thermodynamic data imply that the propensity of N-6-methyl-dAMP for elongation, when incorporated opposite an AP site, is higher than that of dAMP in agreement with a higher promutagenic potential of N-6-methyl-dATP if placed opposite a non-instructional DNA lesion, such as an AP site.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10608 - Biochemistry and molecular biology

Result continuities

  • Project

    <a href="/en/project/GA17-09436S" target="_blank" >GA17-09436S: Translesion DNA synthesis across lesions induced by agents of biological significance. An insight into energetics, kinetics and mechanism</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2018

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    ChemistrySelect

  • ISSN

    2365-6549

  • e-ISSN

  • Volume of the periodical

    3

  • Issue of the periodical within the volume

    46

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    5

  • Pages from-to

    13076-13080

  • UT code for WoS article

    000453576900014

  • EID of the result in the Scopus database