AErP2O7 (A = Rb, Cs) and HEuP2O7.3H2O: Crystal structures, vibrational studies and thermal behaviours
Result description
New diphosphates AErP2O7, A = Rb (1), Cs (2), and HEuP2O7.3H2O(3) have been prepared via soft chemistry route from evaporation of aqueous solution. Their crystal structures have been solved by single crystal diffraction data. The compounds (1) and (2) crystallize in the monoclinic space group P21/c while (3) crystallises in the triclinic space group P - 1 . Crystal structure of (1) and (2) consists of 3D open framework built from [ErO6] octahedra sharing corners with [P2O7] units. The compound (3), on the other hand, exhibits a lamellar structure, in which edge-sharing polyhedra of eight fold coordinated europium form chains along [010].
Keywords
erbiumeuropiumrubidiumcaesiumdiphosphatecrystal structureTG and TDAIR and Raman
The result's identifiers
Result code in IS VaVaI
Result on the web
DOI - Digital Object Identifier
Alternative languages
Result language
angličtina
Original language name
AErP2O7 (A = Rb, Cs) and HEuP2O7.3H2O: Crystal structures, vibrational studies and thermal behaviours
Original language description
New diphosphates AErP2O7, A = Rb (1), Cs (2), and HEuP2O7.3H2O(3) have been prepared via soft chemistry route from evaporation of aqueous solution. Their crystal structures have been solved by single crystal diffraction data. The compounds (1) and (2) crystallize in the monoclinic space group P21/c while (3) crystallises in the triclinic space group P - 1 . Crystal structure of (1) and (2) consists of 3D open framework built from [ErO6] octahedra sharing corners with [P2O7] units. The compound (3), on the other hand, exhibits a lamellar structure, in which edge-sharing polyhedra of eight fold coordinated europium form chains along [010].
Czech name
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Czech description
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Classification
Type
Jx - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
BM - Solid-state physics and magnetism
OECD FORD branch
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Result continuities
Project
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Chemical Crystallography
ISSN
1074-1542
e-ISSN
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Volume of the periodical
42
Issue of the periodical within the volume
5
Country of publishing house
US - UNITED STATES
Number of pages
11
Pages from-to
475-485
UT code for WoS article
000302771800011
EID of the result in the Scopus database
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Basic information
Result type
Jx - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP
BM - Solid-state physics and magnetism
Year of implementation
2012