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Two new halocuprates complexes [CuII(1,4,8,11-tetraazacyclotetradecane)][CuI Cl3] and [H4(1,4,8,11-tetrazacyclotetradecane)][CuI 2Cl6]: synthesis, characterizations and biological studies

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F12%3A00388275" target="_blank" >RIV/68378271:_____/12:00388275 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1007/s00044-011-9968-7" target="_blank" >http://dx.doi.org/10.1007/s00044-011-9968-7</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1007/s00044-011-9968-7" target="_blank" >10.1007/s00044-011-9968-7</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Two new halocuprates complexes [CuII(1,4,8,11-tetraazacyclotetradecane)][CuI Cl3] and [H4(1,4,8,11-tetrazacyclotetradecane)][CuI 2Cl6]: synthesis, characterizations and biological studies

  • Original language description

    Synthesis, crystal structures and biological activities for the new chlorobridged mixed valence CuI/CuII coordination polymer [CuIIcyclam][CuICl3] 1 and [H4cyclam][Cu2 I Cl6] 2 are reported. Compound 1 crystallizes in the orthorhombic system, space groupPccn. Its crystal structure consists of one-dimensional polymer CuIIcyclam?Cl?CuI?Cl?CuIIcyclam. Compound 2 is monoclinic (P21/n)with the tetraprotonated cyclam H4cyclam(4+) in (3,4,3,4)-B conformation. Compound 1 was tested to understand its influenceon enzyme activity, immunomodulation as well as its toxicity and antiglycation potential. Its effect was significant as immunomodulatory and inhibitory activity against b-glucuronidase enzyme.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    BM - Solid-state physics and magnetism

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2012

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Medicinal Chemistry Research

  • ISSN

    1054-2523

  • e-ISSN

  • Volume of the periodical

    21

  • Issue of the periodical within the volume

    12

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    11

  • Pages from-to

    4290-4300

  • UT code for WoS article

    000310030200037

  • EID of the result in the Scopus database