Cyanuric chloride reagent as a chloride ion donor: synthesis, crystal structure, and magnetic properties of [Cu2(2-APM)2(?-Cl)2(?-OCH3)2]n coordination polymer

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F14%3A00440649" target="_blank" >RIV/68378271:_____/14:00440649 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1080/00958972.2014.969250" target="_blank" >http://dx.doi.org/10.1080/00958972.2014.969250</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1080/00958972.2014.969250" target="_blank" >10.1080/00958972.2014.969250</a>

Result language
angličtina
Original language name
Cyanuric chloride reagent as a chloride ion donor: synthesis, crystal structure, and magnetic properties of [Cu2(2-APM)2(?-Cl)2(?-OCH3)2]n coordination polymer
Original language description
A new chloro- and methoxo-bridged Cu(II) coordination polymer, [Cu2(2-APM)2(?-Cl)2(?-OCH3)2]nCH3OH (1), was prepared using in situ formed chloride by the decomposition of cyanuric chloride and 2-aminopyrimidine (2-APM) as a ligand in methanol. Its solid-state structure has been characterized by elemental analysis and single crystal X-ray diffraction. X-ray crystallographic studies reveal that this compound has an extended 2-D supramolecular architecture directed by strong hydrogen bonds and aromatic ???stacking interactions. Compound 1 shows an antiferromagnetic coupling exchange with co upling constants of 58.2 and 41.4 cm-1 between adjacent copper(II) ions, in agreement with the intermetallic distances of 3.0405(5) and 3.6073(5)? found in the crystal structure.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
<a href="/en/project/GA14-03276S" target="_blank" >GA14-03276S: Aspherical effects and their application for statistically correct crystal structure analysis</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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