Polynuclear oxovanadium(IV) Schiff base complex [VOL2]n (L = (5-bromo-2-hydroxybenzyl-2-furylmethyl)imine): synthesis, characterization, crystal structure, catalytic properties and thermal decomposition into V2O5 nano-particles

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F13%3A00391618" target="_blank" >RIV/68378271:_____/13:00391618 - isvavai.cz</a>

Result on the web

<a href="http://dx.doi.org/10.1016/j.inoche.2012.10.029" target="_blank" >http://dx.doi.org/10.1016/j.inoche.2012.10.029</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.inoche.2012.10.029" target="_blank" >10.1016/j.inoche.2012.10.029</a>

Result language

angličtina

Original language name

Polynuclear oxovanadium(IV) Schiff base complex [VOL2]n (L = (5-bromo-2-hydroxybenzyl-2-furylmethyl)imine): synthesis, characterization, crystal structure, catalytic properties and thermal decomposition into V2O5 nano-particles

Original language description

Polynuclear oxovanadium(IV) Schiff base complex was synthesized and characterized by elemental analysis and FT-IR spectroscopy. Its crystal structure has been determined by single crystal X-ray diffraction. The complex has two symmetry independent vanadium centers located on a two-fold axis.Both centers have a distorted octahedral N2O4 coordination sphere. Two Schiff base ligands coordinate to the vanadium center each via one nitrogen and one oxygen atom. The remaining two apices of the octahedron are occupied by oxygen shared by the neighboring vanadium atoms, giving rise to 1D coordination polymer [VOL2]n with the interatomic VV distance 3.7670(6) A. This complex is used as a catalyst for the epoxidation of the cyclooctene.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

BM - Solid-state physics and magnetism

OECD FORD branch

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Project

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Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2013

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Inorganic Chemistry Communications

ISSN

1387-7003

e-ISSN

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Volume of the periodical

27

Issue of the periodical within the volume

JAN

Country of publishing house

NL - THE KINGDOM OF THE NETHERLANDS

Number of pages

6

Pages from-to

82-87

UT code for WoS article

000314618700020

EID of the result in the Scopus database

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