meta-Bridged calix[4] arenes prepared by Friedel-Crafts alkylation
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F17%3A00510509" target="_blank" >RIV/68378271:_____/17:00510509 - isvavai.cz</a>
Alternative codes found
RIV/60461373:22310/17:43914914 RIV/60461373:22810/17:43914914
Result on the web
<a href="https://doi.org/10.1039/c7nj03394j" target="_blank" >https://doi.org/10.1039/c7nj03394j</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c7nj03394j" target="_blank" >10.1039/c7nj03394j</a>
Alternative languages
Result language
angličtina
Original language name
meta-Bridged calix[4] arenes prepared by Friedel-Crafts alkylation
Original language description
By applying electrophilic aromatic mercuration of calix[4]arene the introduction of substituted hydroxymethyl groups at the meta position of the basic skeleton has been achieved. Subsequent intramolecular Friedel–Crafts alkylation led to a novel type of bridged calix[4]arenes with additional symmetrically substituted methylene bridges connecting to the neighbouring aromatic units. Additionally, this new efficient synthetic pathway was also used for the preparation of a double bridged analogue. These compounds with rigidified cavities can complex cations and neutral compounds using CH–pπ and/or cation–π interactions as demonstrated by 1H NMR titration experiments.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10302 - Condensed matter physics (including formerly solid state physics, supercond.)
Result continuities
Project
<a href="/en/project/GA16-13869S" target="_blank" >GA16-13869S: Intramolecularly bridged calixarenes as new building blocks in supramolecular chemistry</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
New Journal of Chemistry
ISSN
1144-0546
e-ISSN
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Volume of the periodical
41
Issue of the periodical within the volume
23
Country of publishing house
GB - UNITED KINGDOM
Number of pages
8
Pages from-to
14738-14745
UT code for WoS article
000415839300087
EID of the result in the Scopus database
2-s2.0-85034862539