On-surface synthesis of organocopper metallacycles through activation of inner diacetylene moieties
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F21%3A00550858" target="_blank" >RIV/68378271:_____/21:00550858 - isvavai.cz</a>
Result on the web
<a href="http://hdl.handle.net/11104/0326166" target="_blank" >http://hdl.handle.net/11104/0326166</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/d1sc03703j" target="_blank" >10.1039/d1sc03703j</a>
Alternative languages
Result language
angličtina
Original language name
On-surface synthesis of organocopper metallacycles through activation of inner diacetylene moieties
Original language description
The design of organometallic complexes is at the heart of modern organic chemistry and catalysis. Recently, on-surface synthesis has emerged as a disruptive paradigm to design previously precluded compounds and nanomaterials. Despite these advances, the field of organometallic chemistry on surfaces is still at its infancy. Here, we introduce a protocol to activate the inner diacetylene moieties of a molecular precursor by copper surface adatoms affording the formation of unprecedented organocopper metallacycles on Cu(111). The chemical structure of the resulting complexes is characterized by scanning probe microscopy and X-ray photoelectron spectroscopy, being complemented by density functional theory calculations and scanning probe microscopy simulations. Our results pave avenues to the engineering of organometallic compounds and steer the development of polyyne chemistry on surfaces.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10302 - Condensed matter physics (including formerly solid state physics, supercond.)
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2021
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Chemical Science
ISSN
2041-6520
e-ISSN
2041-6539
Volume of the periodical
12
Issue of the periodical within the volume
38
Country of publishing house
GB - UNITED KINGDOM
Number of pages
6
Pages from-to
12806-12811
UT code for WoS article
000693387200001
EID of the result in the Scopus database
2-s2.0-85117141758