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Controlling defect chemistry in InTe by saturation annealing

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F22%3A00565306" target="_blank" >RIV/68378271:_____/22:00565306 - isvavai.cz</a>

  • Result on the web

    <a href="https://doi.org/10.1021/acsaem.2c02364" target="_blank" >https://doi.org/10.1021/acsaem.2c02364</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1021/acsaem.2c02364" target="_blank" >10.1021/acsaem.2c02364</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Controlling defect chemistry in InTe by saturation annealing

  • Original language description

    Achieving a precise control of defects in chalcogenide semiconductors is paramount to optimizing their thermoelectric properties. Recently, p-type InTe has emerged as a potential candidate for thermoelectric applications in power generation, mainly due to its extremely low lattice thermal conductivity. Here, we show that the concentration of inherent In vacancies in both single-crystalline and polycrystalline InTe samples can be successfully controlled through saturation annealing. This process, performed on both the In-rich and Te-rich sides of the solidus line at 943, 893, 843, and 943 K, respectively, results in variations in the hole concentration from 4.9 to 8.5 × 1019 cm-3 at 300 K. This narrow density range suggests that the defect chemistry in InTe plays a less critical role in determining its thermoelectric properties compared to other state-of-the-art thermoelectric chalcogenides.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10302 - Condensed matter physics (including formerly solid state physics, supercond.)

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2022

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    ACS Applied Energy Materials

  • ISSN

    2574-0962

  • e-ISSN

  • Volume of the periodical

    5

  • Issue of the periodical within the volume

    11

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    9

  • Pages from-to

    13714-13722

  • UT code for WoS article

    000883759300001

  • EID of the result in the Scopus database

    2-s2.0-85141706023