Crystal structures of XeF2·2PtF4 and XeF2·2PdF4 determined by 3D electron diffraction and structural models of XePtF6
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F25%3A00637886" target="_blank" >RIV/68378271:_____/25:00637886 - isvavai.cz</a>
Result on the web
<a href="https://hdl.handle.net/11104/0368712" target="_blank" >https://hdl.handle.net/11104/0368712</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acs.inorgchem.5c01740" target="_blank" >10.1021/acs.inorgchem.5c01740</a>
Alternative languages
Result language
angličtina
Original language name
Crystal structures of XeF2·2PtF4 and XeF2·2PdF4 determined by 3D electron diffraction and structural models of XePtF6
Original language description
Although the demonstration of noble-gas reactivity represents one of the most significant breakthroughs of 20th-century inorganic chemistry, the first noble-gas compound, XePtF6 (XeF2·PtF4), lacks comprehensive structural characterization, and its structure remains to be elucidated. In this study, the XeF2−PtF4 and XeF2−PdF4 systems were reexplored, resulting in the crystal structure determination of XeF2·2PtF4 and XeF2·2PdF4 by 3D electron diffraction, marking the first successful structural characterization of compounds from these systems. The results of this study thus provide a direct structural link between platinum, palladium, and manganese analogues in the XeF2−MF4 systems and highlight the tetrameric ring structure and cis-chain as likely structural models of XeF2·PtF4.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10302 - Condensed matter physics (including formerly solid state physics, supercond.)
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2025
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Inorganic Chemistry
ISSN
0020-1669
e-ISSN
1520-510X
Volume of the periodical
64
Issue of the periodical within the volume
29
Country of publishing house
US - UNITED STATES
Number of pages
9
Pages from-to
14968-14976
UT code for WoS article
001528617200001
EID of the result in the Scopus database
2-s2.0-105012639684